4.1 SECONDARY BONDING
4.2 LOCAL REINFORCEMENT
4.3 USING PEEL PLY
When composite components come unstuck the type of epoxy that was used sometimes gets held up as the bad guy. It may not always be the case. In fact in many cases its far more likely that the issue of secondary bonding is at the core of the problem.
The term secondary bonding is generally used in composites to describe the process of joining a new uncured laminate to an existing cured laminate, such us taping a bulkhead the hull side or applying an additional layer of reinforcement to a cured laminate.
Technically speaking this is co-bonding.
Secondary bonding refers to the process of joining two or more cured composite parts with an adhesive.
Since this discussion is primarily about the surface preparation for any kind of epoxy bonding with composites the distinction between co-bonding and secondary bonding is not so important.
The term secondary bonding derives from chemistry. It refers to bonds created by the donation and acceptance of electrons between elements. When we abrade the surface of a cured laminate before applying a new laminate it’s tempting to think we are giving the new laminate something to grip onto - a mechanical bond.
In fact we are raising the surface energy to create a chemically active surface that will be attracted to, and bond chemically to the adhesive.
Composites have low free surface energy. That is; they don’t inherently exhibit good bonding characteristics when compared with metals and ceramics.
A mechanical bond can be helpful under some load cases but in general it is a chemical bond that is the objective of surface preparation.
What makes a good bond?
The quality of the bond you achieve is only as good the quality of the chemical reaction at the interface. That chemical reaction is a function of the amount of surface energy available to the
part you are bonding, not just a function of the type of the epoxy you’re using.
“Surface roughness is a secondary outcome and not an important characteristic of a surface over surface cleanliness and surface energy.
Surface chemical composition is more important than roughness. The potential damage that goes along with inducing roughness can be a real problem for composite bonds”.
Giles Dillingham of BTG Labs
When you scratch the surface, grit blast it, tear off the peel ply, or treat it with chemicals you’re creating surface energy. The molecules on the surface of the part are suddenly exposed to a whole new range of molecules in the atmosphere and are chemically unstable. We say the part has surface energy and it is in the ideal state to create a good bond.
But this surface energy is delicate in nature. It can easily be disrupted by contaminants and it degrades over time as the molecules on the surface seek a new equilibrium with the molecules they are newly exposed to.
Careful how you breathe.
The bonding work that takes place at the interface takes place in a very thin layer of molecules, A layer about 6 molecules thick. If someone comes by and sweeps the floor before you’ve made the bond then you’ve probably lost a substantial portion of the surface energy. In fact simply breathing on the surface can leave a film of contaminants between 40 to 100 molecules thick, considerably thicker than the interface where the bond is to take place..
Abrading the surface prior to bonding is a common and effective method of creating surface energy. But its not about creating a rough surface for a mechanical bond. It’s about creating a surface that’s chemically reactive and ready to bond with the liquid molecules in the epoxy.
In fact with high fibre ratio composites the fibres that are critical to the strength of the part are only covered by a very thin layer of resin. Excessive abrading will damage these fibres and reduce the mechanical properties of the part.
How do you determine if a surface is active and ready for bonding?
Measuring the contact angle of water droplets on the surface is a highly reliable and accurate means of determining the amount of surface energy available for bonding.
The shape the droplet takes on the surface is determined by the attraction forces between the droplet and the surface. Where there is weak attraction the droplet beads up to minimise interfacial area. Where there is strong attraction as you have with high surface energy then the droplet is flatter and spreads more widely.
Special instruments that accurately measure the contact angle of water droplets are readily available and are broadly deployed in aerospace and other composites manufacturing operations, But simply spraying some water droplets on the surface will give a good visual indication of the suitability of the surface for bonding.
When you purchase a composite panel or a part that has to be bonded into your boat, or simply prepared for painting, the supplier will usually tell you not to remove the peel ply until you're ready to bond the part. There's a good reason for that.
The surface energy won’t last forever. It degrades over time as the molecules interact with moisture and other contaminates in the atmosphere.
If you prepare a surface late in the day and come back the next morning to make the bond a significant portion of the surface energy will have been lost.
When you peel off the peel ply you have a highly reactive surface with a contact angle of water around 23˚. An hour later the contact angle of the water droplet will b e closer 26˚-27. A day later it's about 30˚.
We’ve only just scratched the surface of this topic. If you’re building composite parts that need to have reliable and consistant mechanical properties then its important that the people on the shop floor understand secondary bonding and are trained in the procedures that will ensure the parts that need to stick will be well stuck.
The information in this article came from a number of sources including a paper presented by Giles Dillingham Ph.D of BTG Labs in Cincinnati, Ohio.
The paper is titled "Understanding and Controlling the Bond Surface in Manufacturing for Reliable Adhesive Bonding of Composites"
Giles has carried out extensive research into secondary bonding and has developed instruments for measuring surface energy.
Giles can be contacted at firstname.lastname@example.org
The use of peel ply over a wet laminate has a number of advantages but one of the most important is that it provides a good surface for secondary bonding without any further preparation required. However two points are important to keep in mind.
The first is that the peel ply must not be removed too soon before creating the bond - as mentioned in the article above.
The second is that the peel ply needs to provide the right amount of resistance when you remove it from the part. Some peel plys have a release agent to make them easier to remove. If there is too much release agent and the peel ply comes away too easily it will not provide enough surface energy to the part. On the other hand if the peel ply is too difficult to tear off it may pull chunks of resin away from the surface exposing the bare reinforcement.
If your peel ply is not coming away with the right amount of resistance report it to your supplier, they may not be aware of the problem.
I had a look for some good videos about removing peel ply on You Tube. In the first two I came across the commentator was tearing the ply away from a small part while repeatedly rubbing his bare hand over the freshly exposed surface, and simultaneously saying that the surface is now ready for gel coat or bonding without any further preparation. Be careful where you get your information from.
I was helping some friends build a cedar strip planked cat back in the 1980's. We thought it was really clever to go to the local dress material shop and buy some cotton fabric at a fraction of the cost of peel ply from our composites supplier.
As far as I know the boat is still afloat but I don't recommend this as a clever idea.
For an introduction to peel ply check this short video clip from Fibre Glast
Check the Fibre Glast web site for materials and a series of well produced composites tutorials.
Foam cored composited sandwich panels are very good at providing high stiffness for low weight. They are not good at supporting highly concentrated loads in shear, compression or tension. Items like sail controls (including winches and sheet tracks), cleats, chainplates, rudder gudgeons, windows, hatches and mast support all require that that the laminate be locally reinforced to support the concentrated loads.
There are two ways to deal with this;
1. CONSOLIDATED LAMINATE OR SINGLE SKIN
The inner and outer skins of the laminate be joined together by removing the foam core and creating a consolidated laminate in the area of the fitting. The area of consolidated laminate is then reinforced by wet laminating additional layers of reinforcement, possibly in conjunction with a solid backing plate from G10 or Coosa board.
Note that consolidated laminate is often referred to as solid laminate or single skin laminate. Routing out the core in the way of bolts or screws and filling with epoxy does not constitute solid or consolidated laminate.
2. By replacing the foam core with a solid high density material between the two skins.
G10 is a composite fibreglass/epoxy laminate laid up under pressure and available in sheet form. It is an ideal material to use for inserts in foam/core replacement and backing plates in way of sail controls and other deck fittings.
Coosa is a composite made of high-density, polyurethane foam reinforced with layers of fiberglass. It is available in sheet form and is ideal for core replacement under highly loaded fittings.
HD PVC FOAM
High Density PVC core is often specified as a replacement in for lower density foam core where there are concentrated load in way of hardware items.
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